Your children are dual citizens by birth likely, you'd just need to register their births with the US consulate nearest you. Eligibility will of course depend on how many years your wife has been away from the US I think.
While you're at the US consulate, you can also fill out the paperwork for her to sponsor you to immigrate to the US.
Here's the link to the
Consulate in Toronto
And info about spousal sponsorhip
http://www.amcits.com/immigration_usa_relative.asp