Umm, of course she is eligible for TD. She needs a visa, which can be obtained at US consulate (preferably in Bangladesh, but can be in Canada).
Proff of your TN, and proof of marriage is needed.
This site is a travel site and not best source for these topics: TN and TD info: http://forums.immigration.com/forumdisp ... -TN-Status For US/Cdn taxes and SS/CPP:forums.serbinski.com/index.php US Marriage-based Immigration: visajourney.com